"Metall." . . . . "Metal vapors." . . "Configurations." . . "Reactive gases." . . "Chemical reaction, Conditions and laws of." . . . . "The use of new advanced solid rocket propellant constituents, such as, e.g., boron as HEDM and ammonium nitrate as replacement for halogen-containing oxidants, requires knowledge of their combustion characteristics. To this end experimental rate coefficient k measurements on individual important Al and B species reactions were made in the 300-1800 K temperature range using a high- temperature fast-flow reactor. Temperature dependent rate coefficient expressions k(T) = AT(super n)exp( -E/RT) are found for the reactions between AlO and CH4, O2; Al and N2O: AlCl and N2O, CO2, SO 2; BCl and N2O, SO2; BO and CO2. To allow semi-empirical predictions for further metal oxidation reactions, two semi-empirical theories have been developed and utilized. These are Semi-Empirical Configuration Interaction theory for prediction of E from one species to another and metals-Transition State Theory for prediction of k(T) from k at one temperature. Dual military-civilian applications of this work are discussed. jg p. 1."@en . . . . . . . . . . . . . . . . . "Electronic books"@en . . "Gas-phase metal reactions" . "Gas-phase metal reactions"@en . . . . . . . "Gas-phase metal reactions : Symposium : Papers"@en . . . . . . . . . . . . . . . . . . . . . "Kongress (New York, 1991)" . . . . . . . . . . . . "Gas-Phase Metal Reactions"@en . . . "Gas Phase Metal Reactions"@en . "Oxidation reduction reactions." . . "Halogens." . . "Chemical reactions." . . "Sulfur oxides." . . "Aluminum oxides." . . "Military personnel." . . "Molecules." . . "Methane." . . "Predictions." . . "Ammonium nitrate." . . "SCIENCE / Chemistry / Inorganic" . . "Boron." . . "Phase." . . "Physical Chemistry." . . "Gasreaktion." . . "Chlorides." . . "Gases." . . "Aufsatzsammlung." . . "Density." . . "ACS. Physical Chemistry Division." . . "Nitrogen oxides." . . "Gasphasenreaktion." . . "Interactions." . . "Inorganic Chemistry." . . "Atomic and Molecular Physics and Spectroscopy." . . "Carbon dioxide." . . "Chemical reactions, Conditions and laws of." . . "Metals." . . "Combustion." . . "Réactions chimiques Mécanismes." . . "Solid rocket propellants." . . "Solid Rocket Propellants." . "Métaux." . . "RENSSELAER POLYTECHNIC INST TROY NY Dept. of CHEMICAL ENGINEERING." . . "High energy." . .